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Fluoroalkylphosphates for use in electrochemical cells

申请公布号:EP1178050(A3)

申请号:EP20010115786

申请日期:2001.07.11

申请公布日期:2002.09.25

申请人:
MERCK PATENT GMBH

发明人:HEIDER, UDO, DR.;SCHMIDT, MICHAEL, DR.;KUEHNER, ANDREAS, DR.;SARTORI, PETER, PROF. DR.;IGNATYEV, NIKOLAI, DR.

分类号:C07F9/38;C07C211/13;C07C211/14;C07C211/63;C07F9/28;C07F9/52;C07F9/54;H01G9/02;H01G9/022;H01G11/08;H01G11/54;H01G11/60;H01G11/62;H01G11/84;H01M6/16;H01M10/05;H01M10/0568;H01M10/0569;(IPC1-7):C07F9/28;H01M10/40

主分类号:C07F9/38

摘要:New fluoroalkyl-fluoro-phosphates (I), with a mono- to tri-valent cation (except lithium, sodium, cesium, potassium and silver), especially a (substituted) ammonium, phosphonium, aminophosphonium, triaminocarbonium, triarylcarbonium, rubidium or tropylium cation, are new. New fluoroalkyl-fluoro-phosphates of formula (I), with a mono- to tri-valent cation (except lithium, sodium, cesium, potassium and silver), especially a (substituted) ammonium, phosphonium, aminophosphonium, triaminocarbonium, triarylcarbonium, rubidium or tropylium cation, are new: Mn+(PFx(CyF2y+1-zHz)6-x)n<-> (I) x = 1-6; y = 1-8; z = 0 to 2y+1; n = 1-5; Mn<+> = a mono- to tri-valent cation, especially NR<1>R<2>R<3>R<4>, PR<1>R<2>R<3>R<4>, P(NR<1>R<2>)kR<3>mR<4>4-k-m, C(NR<1>R<2>)(NR<3>R<4>)(NR<5>R<6>), C(Aryl)3, rubidium (Rb) or tropylium cation, with the exception of lithium, sodium, cesium, potassium and silver; k = 1-4; m = 0-3; k+m = 1-4; R<1-6> = hydrogen (H) or 1-8 carbon (C) alkyl or aryl, optionally partly substituted by fluorine (F), chlorine (Cl) or bromine (Br). Independent claims are also included for: (a) the preparation of (I); (b) electrolytes for primary batteries, secondary batteries, capacitors, supercapacitors and galvanic cells, which contain compound(s) (I).

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