NOVEL FERROCENE COMPOUND AND ITS PREPARATION

申请公布号：JPS60188393(A)

申请号：JP19840044662

申请日期：1984.03.08

申请公布日期：1985.09.25

申请人：

KAWAKEN FINE CHEMICAL KK

发明人：KASAHARA AKIRA;IZUMI TAEKO;SHIMIZU IWAO

分类号：H01B1/12;C07F17/02

主分类号：H01B1/12

摘要：NEW MATERIAL:The compound of formula I (R1-R5 are H or methyl; R6 is H, methyl or Cl). EXAMPLE:1-Phenyl-1'-(2,5-benzoquinonyl)ferrocene. USE:An organic electroconductive material. PREPARATION:The objective compound can be prepared by (1) reacting ferrocene of formula II with the diazonium salt of formula III (X is inorganic acid residue), (2) reacting the resultant compound of formula IV with the diazonium salt compound of formula V to obtain the compound of formula VI, and (3) demethylating and oxidizing the compound with boron tribromide and silver oxide.

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