COMPOSITIONS USEFUL FOR OLEFIN POLYMERIZATION AND PROCESSES AND THEREWITH
申请公布号:CA2154823(A1)
申请号:CA19952154823
申请日期:1995.07.27
申请公布日期:1996.03.17
发明人:PETTIJOHN, TED M
分类号:C08F4/642;C08F4/60;C08F4/626;C08F4/646;C08F4/659;C08F4/6592;C08F10/00;C08F110/02
主分类号:C08F4/642
摘要:A composition, which can be used as catalyst for producing an olefin polymer having a multimodal molecular weight distribution, is provided that comprises a transition metal-containing catalyst, a metallocene, and a boroncontaining organoaluminoxane, wherein each component of the composition is present in an effective amount so that an olefin polymer having a multimodal molecular weight distribution can be produced using the composition as catalyst, preferably in the presence of a cocatalyst. Also provided is a process for preparing the composition which comprises: (1) contacting a transition metal-containing catalyst with an organoaluminoxane dispersed in a solvent to form a slurry; (2) combining the slurry with a boroxine to prepare a combination of a transition metal-containing catalyst and boron-containing organoaluminoxane; and (3) contacting the combination with a metallocene. Further provided is a process for polymerizing an olefin to prepare an olefin polymer using the composition.