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Methods of using hydrogen peroxide for in-situ chemical oxidation treatment of soil and groundwater

申请公布号:US2016144413(A1)

申请号:US201615011174

申请日期:2016.01.29

申请公布日期:2016.05.26

申请人:
Cronk Gary

发明人:Cronk Gary

分类号:B09C1/08;B09C1/00

主分类号:B09C1/08

地址:Santa Ana CA US

摘要:Disclosed are methods of custom stabilization of the hydrogen peroxide used in the safe in-situ treatment of soil and groundwater. In one embodiment, disclosed is a method of in-situ chemical oxidation treatment of soil and/or groundwater wherein the hydrogen peroxide has been stabilized with carboxylate salt (e.g., sodium citrate, sodium malonate, or sodium phytate). Procedurally, chemical daylighting is avoided by: (a) mixing a batch of aqueous hydrogen peroxide solution with a carboxylate salt; (b) injecting the solution into a subterranean location; (c) allowing iron that is naturally present in the in-situ environment to mix with the solution; (d) controlling the subsurface pressure and temperature within the in-situ environment; (e) manipulating the concentration of carboxylate salt in the remainder of the hydrogen peroxide batch (as necessary), wherein the concentration of carboxylate salt defines the life-span of the hydrogen peroxide, and helps to control the subsurface reaction and minimize the possibility of chemical daylighting

主权项:1. A method of in-situ chemical oxidation comprising the steps of: (a) mixing an aqueous hydrogen peroxide solution with a carboxylate salt; (b) injecting a portion of the solution into a subsurface in-situ environment; (c) allowing iron that is present in the in-situ environment to catalyze the hydrogen peroxide in the solution; and, (d) measuring or observing a condition in the in-situ environment.

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