OXYGEN-CONTAINING CYCLIC COMPOUND AND METHOD FOR PRODUCING THE SAME
申请公布号:JP2011201847(A)
申请号:JP20110008899
申请日期:2011.01.19
申请公布日期:2011.10.13
发明人:YAMASHITA HIROSHI;HATORI MAKIKO;MITSUKURA YUMI
分类号:C07D307/33;C07B61/00;C07C45/67;C07C49/597;C07D407/04;C07D409/04
主分类号:C07D307/33
摘要:PROBLEM TO BE SOLVED: To provide a method for efficiently producing an oxygen-containing cyclic compound useful as functional chemicals such as pharmaceuticals, agrochemicals and electronic materials.SOLUTION: Furans having same or different substituents on 2,5-positions, 5-membered lactones having substituent on 4-position and/or 2-cyclopentenones having substituent on 3-position are produced by reacting an aromatic compound with a 4-oxocarboxylic acid in the presence of a catalyst. A solid acid catalyst such as zeolite can be used as the catalyst, and the zeolite is preferably β-zeolite etc. The reaction is more efficiently performed by using microwave irradiation.
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