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OXYGEN-CONTAINING CYCLIC COMPOUND AND METHOD FOR PRODUCING THE SAME

申请公布号:JP2011201847(A)

申请号:JP20110008899

申请日期:2011.01.19

申请公布日期:2011.10.13

申请人:
NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE & TECHNOLOGY

发明人:YAMASHITA HIROSHI;HATORI MAKIKO;MITSUKURA YUMI

分类号:C07D307/33;C07B61/00;C07C45/67;C07C49/597;C07D407/04;C07D409/04

主分类号:C07D307/33

摘要:PROBLEM TO BE SOLVED: To provide a method for efficiently producing an oxygen-containing cyclic compound useful as functional chemicals such as pharmaceuticals, agrochemicals and electronic materials.SOLUTION: Furans having same or different substituents on 2,5-positions, 5-membered lactones having substituent on 4-position and/or 2-cyclopentenones having substituent on 3-position are produced by reacting an aromatic compound with a 4-oxocarboxylic acid in the presence of a catalyst. A solid acid catalyst such as zeolite can be used as the catalyst, and the zeolite is preferably β-zeolite etc. The reaction is more efficiently performed by using microwave irradiation.

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