PROCESS FOR THE PREPARATION OF POLYOLS
申请公布号:KR20090017990(A)
申请号:KR20080079712
申请日期:2008.08.14
申请公布日期:2009.02.19
发明人:LORENZ KLAUS;WERNER ARNULF;EICHMANN MARCUS
分类号:C08G18/48;C08G18/08;C08G18/16;C08G18/28
主分类号:C08G18/48
摘要:A method for manufacturing polyol is provided to obtain ethylene oxide-containing polyol economically by using alkali or alkaline earth metal hydroxide, and carboxylate or hydride catalyzing. A method for manufacturing polyol comprises (1) a step for base-catalyzing (a) at least one alkylene oxide in at least one polyfunctional initiator having (b) a Zerewitinoff-active hydrogen atom, in the presence of (c) at least one catalyst of 0.004-0.5 weight % concentration based on the based on amount of the final product; and (2) a step for neutralizing the alkaline polymerization-active center of a crude alkylene oxide addition product by adding 66-100 mole % of a sulfuric acid contained in the crude polymer, based on the acid used.