Catalysts and methods for catalytic oxidation
申请公布号:US2003036473(A1)
申请号:US20020228854
申请日期:2002.08.27
申请公布日期:2003.02.20
发明人:BUSCH DARYLE HADLEY;COLLINSON SIMON ROBERT;HUBIN TIMOTHY JAY
分类号:B01J31/16;B01J31/18;C07C45/29;C07C45/30;C07D471/08;C07D471/22;C07D487/08;C07F13/00;C11D3/39;(IPC1-7):B01J31/00
主分类号:B01J31/16
摘要:Catalytic systems and methods for oxidizing materials in the presence of metal catalysts (preferably manganese-containing catalysts) complexed with selected macropolycyclic rigid ligands, preferably cross-bridged macropolycyclic ligands. Included are using these metal catalysts in such processes as: synthetic organic oxidation reactions such as oxidation of organic functional groups, hydrocarbons, and heteroatoms, including enantiomeric epoxidation of alkenes, enynes, sulfides to sulfones and the like; oxidation of oxidizable compounds (e.g., stains) on surfaces such as fabrics, dishes, countertops, dentures and the like; oxidation of oxidizable compounds in solution, dye transfer inhibition in the laundering of fabrics; and further in the bleaching of pulp and paper products.
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