POLYESTERPOLYOL COMPOSITION AND POLYURETHANE FOAM
申请公布号:JP2000038441(A)
申请号:JP19980206542
申请日期:1998.07.22
申请公布日期:2000.02.08
发明人:MITSUI YOSHIO;KATO TOSHIHIRO
分类号:C08G63/688;C08G18/42;C08G18/46;(IPC1-7):C08G63/688
主分类号:C08G63/688
摘要:PROBLEM TO BE SOLVED: To obtain a polyesterpolyol having sulfo groups and/or sulfonate groups and useful for obtaining polyurethane foams having good dimensional stability at low temperature by reacting a carboxylic acid such as a sulfo group, etc. SOLUTION: This polyesterpolyol composition having sulfo groups and/or sulfonate groups in the molecular skeleton is obtained by reacting a carboxylic acid having a sulfo group and/or a sulfonate group or its esterification product (for example, a dialkylsulfosuccinic acid). The compound having a sulfo group and/or a sulfonate group is preferably contained in an amount of 0.1-30 wt.% based on the weight of the reaction mixture. A polyhydric alcohol used for the esterification reaction of the acid component includes ethylene glycol. The hydroxy group value of the polyesterpolyol can be changed by changing the molar ratio of the acid component to the alcohol component, but preferably is 50-500 (KOH mg/g). The acid value is <=4.0 (KOH mg/g), and the water content is preferably <=0.1%.