Process for producing a polyarylene sulfide.,申请号EP19870307175-传众专利搜索

Process for producing a polyarylene sulfide.

申请公布号：EP0259984(A1)

申请号：EP19870307175

申请日期：1987.08.13

申请公布日期：1988.03.16

申请人：

KUREHA KAGAKU KOGYO KABUSHIKI KAISHA

发明人：IWASAKI, TAKAO;IIZUKA, YO;KATTO, TAKAYUKI;SHIIKI, ZENYA

分类号：C08G75/02;C08G75/06;(IPC1-7):C08G75/02

主分类号：C08G75/02

摘要：<p>High-molecular-weight or ultra-high-molecular-weight PAS is prepared by: (1) a preliminary polymerization step of subjecting an alkali metal sulfide and a dihalo aromatic compound to dehalogenation and sulfidation in a system where the amount of an aprotic organic polar solvent used is from 0.2 to 5 kg per mol of the alkali metal sulfide charged and where from 0.5 to 5 mol of water is present per kg of the organic polar solvent, until the conversion of the dihalo aromatic compound charged reaches from 50 to 98 mol% and the melt viscosity of the resultant prepolymer reaches from 0.5 to 30 Pas (from 5 to 300 poise) (as measured at 310 DEG C under a shear rate of 200 sec<-><1>); and (2) a two phase separated polymerization step comprising: (I) (i) adding water to the resultant reaction mixture such that from 5.5 to 15 mol of water is present per kg of the organic polar solvent in the reaction system without separating the resultant prepolymer from the reaction system, or (ii) separating the resultant prepolymer, dispersing the thus separated prepolymer in an aprotic organic polar solvent containing from 5.5 to 15 mol of water per kg of the organic polar solvent such that from 0.5 to 3.5 mol of arylene group(s) therein is present per kg of the organic polar solvent; and (II) (i) heating and maintaining the reaction system for at least 10 minutes at a temperature (T1) of from 257 to 290 DEG C while stirring, the reaction system from step (I) (ii) being in a strongly alkaline condition (pH of the 10-fold diluted dispersion with water being not less than d</p>