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Process for spin dyeing polymers or copolymers of acrylonitrile with quaternized heterocyclic diazo dye and tetrafluoro-borate anion

申请公布号:US4382801(A)

申请号:US19810330745

申请日期:1981.12.14

申请公布日期:1983.05.10

申请人:
CIBA-GEIGY CORPORATION

发明人:LOEW, PETER

分类号:D01F6/54;C09B44/10;C09B44/14;C09B44/16;C09B44/20;C09B69/06;D01F1/06;(IPC1-7):C09B44/10;D06P3/60

主分类号:D01F6/54

摘要:The invention relates to a process for spin dyeing polymers of acrylonitrile or copolymers containing predominantly acrylonitrile, which process comprises adding to the spinning solution a monocationic dye salt of the formula <IMAGE> wherein D is the group of atoms necessary to close a 5-membered heterocyclic ring containing two N-atoms, or to close a 6-membered heterocyclic ring, which rings may optionally contain fused benzene rings, or is the group of atoms necessary to close a benzthiazole ring, and Q is the radical of a carbocyclic or heterocyclic aromatic coupling component, and R1 is alkyl, aralkyl or aryl. The yellowish-red transparent fibres obtained have excellent fastness properties.

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